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Valorization of glycerol via esterification with acetic acid to produce diand tri-acetin
Name: Wirat Kandee
Organization :
Chulalongkorn University. Faculty of Engineering
Email :
awirat.kand@outlook.com
Name: Kanokwan Ngaosuwan
Organization :
Rajamangala University of Technology Krungthep. Faculty of Engineering
Email :
bkanokwan.n@mail.rmutk.ac.th
Name: Weerinda Mens
Organization :
Rajamangala University of Technology Thanyaburi. Faculty of Engineering
Name: Doonyapong Wongsawaeng
Organization :
Silpakorn University. Faculty of Engineering and Industrial Technology
Name: Worapon Kiatkittipong
Organization :
Silpakorn University. Faculty of Engineering and Industrial Technology
Name: Quitain, Armando T.
Organization :
Kumamoto University. Japan Research Organization for Advanced Science and Technology (IROAST)
Name: Kida, Tetsuya
Organization :
Kumamoto University. Faculty of Advanced Science and Technology
Name: Suttichai Assabumrungrat
Organization :
Chulalongkorn University. Faculty of Engineering
keyword:
Acetins
LCSH:
Glycerin
LCSH:
Esterification
LCSH:
Acetic acid
LCSH:
Chemical processes
LCSH:
Renewable energy sources
Abstract:
A renewable fuel, biodiesel, is an environmentally friendly and alternative resource for local
availability which has potential to replace diesel. However, 10 kg of biodiesel production via
transesterification produces 1 kg of glycerol as a byproduct. Crude glycerol from this process
requires the distillation unit to increase purity of glycerol which is an extensive energy
requirement. The glycerol esterification is one of potential process to produce bio-additive fuel
as diacetin (DA) and triacetin (TA). The solid acid catalysts, namely, graphene oxide (GO),
reduced graphene oxide (rGO) and 12 tungstophosphoric acid (TPA) were selected to catalyze
the glycerol esterification using acetic acid to glycerol molar ratio of 6:1, catalyst loading of 1
wt.% and reaction temperature of 110 °C for 2 h. It was found that TPA and rGO offered high
glycerol conversion as well as high selectivity of DA and TA. The characterization results of
catalyst supported their catalytic activities in term of active function groups including
sulfonated group for rGO and heteropoly acid group for TPA
King Mongkut's University of Technology North Bangkok. Central Library
Address:
BANGKOK
Email:
library@kmutnb.ac.th
Created:
2024
Modified:
2025-03-05
Issued:
2025-03-05
BibliograpyCitation :
In Thai Institute of Chemical Engineering and Applied Chemistry. The 33st Thai Institute of Chemical Engineering and Applied Chemistry International Conference (TIChE 2024) (pp.76-84). Bangkok : Thai Institute of Chemical Engineering And Applied Chemistry
eng
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| Title | Contributor | Type |
|---|---|---|
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| Title | Contributor | Type |
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Suttichai Assabumrungrat
| Title | Contributor | Type |
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