Therakanya Sripho. Efficiency enhancement of chemical recycling process of degradable polylactic acid by employing microwave and magnetic nanoparticle catalyst. Master's Degree(Engineering Technology). Thammasat University. Thammasat University Library. : Thammasat University, 2015.
Efficiency enhancement of chemical recycling process of degradable polylactic acid by employing microwave and magnetic nanoparticle catalyst
Abstract:
The aim of this research is enhancement PLA chemical recycling efficiency.
Glycolysis reaction via ethylene glycol was selected as chemical recycling method.
Microwave irradiation and magnetic nano particle (MNPs) catalyst were introduced to
improve the performance of glycolysis reaction. 1H-NMR, GPC, FT-IR, and SEM
were used for characterization chemical structure and degree of polymerization (DP)
of products. The results reveal that glycolyzed PLA (GlyPLA) is the main products
from this recycling process. The reaction time can be dramatically decreased when
microwave irradiation is employed. Additionally, dramatic decreasing of GlyPLA
chain lengths is achieved when MNPs catalyst is introduced in the reaction.
However, chemical structures of the GlyPLA are not affected by employing
microwave irradiation and MNPs catalyst. Therefore, employing microwave
irradiation as a heating source and MNPs as a catalyst can enhance the performance of
PLA chemical recycling
Thammasat University. Thammasat University Library