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Joongjai Panpranot. Effect of transition metal promoted on vanadium phosphorus oxide (VPO) catalysts in the partial oxidation of n-Pentane. (). King Mongkut's University of Technology North Bangkok. Central Library. : , 2017.
Effect of transition metal promoted on vanadium phosphorus oxide (VPO) catalysts in the partial oxidation of n-Pentane
Name: Suchanuch Pisuttangkul
Organization :
Chulalongkorn University. Faculty of Engineering
Email :
Suchanut.P@student.chula.ac.th
Name: Joongjai Panpranot
Organization :
Chulalongkorn University. Faculty of Engineering
keyword:
Vanadium phosphorus oxide
LCSH:
Transition metals
-- Analysis
LCSH:
Maleic anhydride
LCSH:
Phthalic anhydride
Abstract:
Vanadium phosphorus oxide (VPO) catalysts were promoted with different
transition metals (M = Co, Bi, Fe, and Mn) for the partial oxidation of n-pentane to maleic
anhydride (MA) and phthalic anhydride (PA). The catalysts were prepared by precipitation
method and characterized by X-ray diffraction (XRD), scanning electron microscopy
(SEM), N2-physisorption, X-ray fluorescence (XRF), and X-ray photoelectron
spectroscopy (XPS). The catalytic performances were evaluated using a fixed bed reactor
with 1.7% n-pentane in air at 673 K and the liquid products were analyzed by a gas
chromatography-mass spectrometry (GC-MS). All the transition metal promoted VPO
exhibited higher conversion of n-pentane and higher selectivity of MA and PA than the
unpromoted one. The best catalytic performances were obtained over the Mn doped VPO
catalyst with 47.1% conversion of n-pentane at 3 h and selectivity of MA and PA 59.7%
and 23.2%, respectively. The improved catalyst performances were suggested to be due to
the small crystallite size and high specific surface areas of the modified VPO and the
decrease in vanadium oxidation state.
King Mongkut's University of Technology North Bangkok. Central Library
Address:
BANGKOK
Email:
library@kmutnb.ac.th
Created:
2017
Modified:
2562-08-13
Issued:
2019-08-13
บทความ/Article
application/pdf
BibliograpyCitation :
In Chemical Society of Thailand under the Patronage of Her Royal Hghness Princess Chulabhorn Mahidol and King Mongkut's University of Technology North Bangkok Faculty of Applied Science. Pure and Applied Chemistry International Conference (PACCON 2017) (pp.680-685). Bangkok : Chemical Society of Thailand under the Patronage of Her Royal Hghness Princess Chulabhorn Mahidol
eng
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Suchanuch Pisuttangkul
| Title | Contributor | Type |
|---|---|---|
| Effect of transition metal promoted on vanadium phosphorus oxide (VPO) catalysts in the partial oxidation of n-Pentane
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Suchanuch Pisuttangkul;Joongjai Panpranot | บทความ/Article |
Joongjai Panpranot